I'm playing around my edges of understanding so take it from that perspective.
Load goes to stiffness, if that purlin is a slight bit high it will deflect until it can bear the load, the resulting higher load goes to that section of truss which will bear the load or deflect until it shares the load with the next high spot. Within reason I think it tends to become pretty uniform. These formulas allow for some of that.
I see a uniformly distributed load on the top chords of your truss. There are 4 top chord members, heel to web, web to ridge, ridge to web, web to heel. In other words there are 4 shorter spans being checked for combined loading rather than two longer ones, but in total 2 situations, upper and lower parts of a top chord. There is also an eccentric tension load caused by the raised tie beam. In the bottom member of the top chord there is a compressive axial load running down the grain of the member. Then there are two bending loads on the side of the chord, the uniform load of the Sip and the tension pull from the raised tie. That one gets really interesting. Quantifying all that is beyond me.
At its simplest it is this. If a member is loaded axially as a column, and in bending as a beam, the combined effects of both loads cannot equal more than one member.
(P/A)/c +(M/S)/fb <1
P= the axial load
A= breadth x depth of member, area
c= allowable compressive load.
Looking at that side of the equation, we've taken the load, P, and divided it by the area of the column, that gives us the load in pounds per square inch. Dividing it by the allowable load, in psi, gives the percentage of the allowable column load is being used.
M= bending moment in inch pounds
S= section modulus of the beam, bd
2/6
fb= allowable bending stress
This is a beam bending check, find how hard the side bending load is and check it against the allowed bending load for that sized beam. Dividing gives the percentage of allowed bending.
Putting the two halves of the formula together, if the top chord is using half its available strength taking care of the compressive load then it can only use half of its strength or less resisting a bending load. Adding the percentage of compressive strength used and the percentage of bending strength used has to equal less than the 1 member you propose or you need a bigger timber. (P/A)/fc +(M/S)/fb <1
The formula gets more complicated as the chords get longer and more slender. You'll see Euler formulas mentioned often. This is the best mathmatical model for long slender columns buckling stress, it begins modifying Fc in the simple formula basically coming into play when length/depth ratio gets above 1/11. It is this output on the calc "Max allowable buckling stress (psi)
P/A=(.329*E))/(Span/D1)2". I have you visually double checking Fc and FcE, the Euler buckling stress.
Notice it uses the stiffness of the column (E) in considering its buckling strength. Actually it uses about 1/3 of the stiffness (.329). Thats a safety. That's the 1944 formula, in '05 they switched to using Emin, a new design value for use in columns... it equals about 1/3 E

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To look at it another way, short fat columns crush, Fc is the crushing strength of the wood. Longer or more slender columns buckle, FcE. Check both. Euler may say the column can take 6000 psi and not buckle. Fc might say yes, but it will have crushed. or vice versa.
A post with a brace coming into it is another situation of a member with combined axial and bending loads.